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Welcome to the Bunnings Workshop community @suejems. It's brilliant to have you join us, and many thanks for your question about removing rust from a door frame.
It would be very helpful for our members when offering advice if they could see what you're working with. Please let me know if you need a hand uploading images.
Typically, rust forms on steel when exposed to moisture, so it sounds like a painted coating might have deteriorated. The typical method of rust removal is through abrasion and sanding. Once the rust has been sanded back, it can be treated with a rust converter. After the rust converter has had time to work, the area can be primed and painted to exclude moisture from the area and improve its appearance.
Please let me know if you have any questions.
Mitchell
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